Gate formation with varying work function layers

ABSTRACT

A structure and a method of forming are provided. A first work function layer is formed over a first fin and terminates closer to the first fin than an adjacent second fin. A second work function layer is formed over the first work function layer and terminates closer to the second fin than the adjacent second fin. A third work function layer is formed over the first work function layer and the second fin. A conductive layer is formed over the third work function layer.

PRIORITY CLAIM AND CROSS-REFERENCE

This application is a divisional of U.S. application Ser. No. 15/609,886, filed on May 31, 2017, now U.S. Pat. No. 10,644,134, which application is hereby incorporated herein by reference.

BACKGROUND

Metal-Oxide-Semiconductor (MOS) devices are basic building elements in integrated circuits. An existing MOS device typically has a gate electrode formed of polysilicon doped with p-type or n-type impurities, using doping operations such as ion implantation or thermal diffusion. The work function of the gate electrode may be adjusted to the band-edge of silicon. For an n-type Metal-Oxide-Semiconductor (NMOS) device, the work function may be adjusted to close to the conduction band of silicon. For a P-type Metal-Oxide-Semiconductor (PMOS) device, the work function may be adjusted to close to the valence band of silicon. Adjusting the work function of the polysilicon gate electrode can be achieved by selecting appropriate impurities.

MOS devices with polysilicon gate electrodes exhibit carrier depletion effect, which is also known as a poly depletion effect. The poly depletion effect occurs when the applied electrical fields sweep away carriers from gate regions close to gate dielectrics, forming depletion layers. In an n-doped polysilicon layer, the depletion layer includes ionized non-mobile donor sites, wherein in a p-doped polysilicon layer, the depletion layer includes ionized non-mobile acceptor sites. The depletion effect results in an increase in the effective gate dielectric thickness, making it more difficult for an inversion layer to be created at the surface of the semiconductor.

The poly depletion problem may be solved by forming metal gate electrodes, wherein the metallic gates used in NMOS devices and PMOS devices may also have band-edge work functions. Accordingly, the resulting metal gates include a plurality of layers to suit the requirements of the NMOS devices and PMOS devices.

BRIEF DESCRIPTION OF THE DRAWINGS

Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.

FIGS. 1 through 20B illustrate various intermediate stages in the formation of a Fin Field-Effect Transistor (FinFET) in accordance with some embodiments.

FIG. 21 illustrates a flow chart of a process for forming a FinFET in accordance with some embodiments.

DETAILED DESCRIPTION

The following disclosure provides many different embodiments, or examples, for implementing different features of the invention. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.

Further, spatially relative terms, such as “underlying,” “below,” “lower,” “overlying,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.

Transistor and the methods of forming the same are provided in accordance with various exemplary embodiments. The intermediate stages of forming the transistors are illustrated in accordance with some embodiments. Some variations of some embodiments are discussed. Throughout the various views and illustrative embodiments, like reference numbers are used to designate like elements. In the illustrated exemplary embodiments, the formation of Fin Field-Effect Transistors (FinFETs) is used as an example to explain the embodiments of the present disclosure. Planar transistors may also adopt the concept of the present disclosure.

FIGS. 1 through 20B illustrate various intermediate stages in fabricating FinFETs in accordance with some embodiments of the present disclosure. The process described herein relates to forming multiple transistors having different operating characteristics that may share a common gate. For example, in an embodiment a p-type transistor and an n-type transistor may share a common gate in, for example, an inverter. In situations such as these, it may be desirable to adjust the gate electrode such that the work function of the gate electrode is tuned for the particular operating characteristics. Throughout the description, when a metal layer is referred to as a work-function metal, it indicates it has a work function that fits the type of the respective FinFET, and its location in the metal gate allows its work function to affect or determine the work function of the respective FinFET. For example, when the FinFET is an n-type FinFET, the work-function metal preferably has a low work function, which is lower than the mid-gap work function (about 4.5 eV). The work function of the respective work-function metal may be referred to as an n-work function, which is lower than about 4.3 eV, and may be in the range between about 3.9 eV and about 4.3 eV. When the FinFET is a p-type FinFET, the work-function metal has a high work function, which is higher than the mid-gap work function. The work function of the respective work-function metal may be referred to as a p-work function, which is higher than about 4.5 eV, and may be in the range between about 4.7 eV and about 5.1 eV.

In the description that follows, examples are provided assuming a first fin 210 _(A) (see, e.g., FIG. 20B) is formed having three work function layers and a second fin 210 _(B) (see, e.g., FIG. 20B) is formed having one work function layer. In this example, the first fin 210 _(A) is assumed to be a p-type FinFET and the second fin 210 _(B) is assumed to be a n-type FinFET. Three work function layers will be formed over the first fin 210 _(A) for the p-type FinFET and one work function layer will be formed over the second fin 210 _(B) for the n-type FinFET. The three work function layers may be, for example, two layers of p-type work function metals (such as TiN or other p-type work function metals) and one layer of an n-type work function metal (such as TiAl or other n-type work function metals), whereas the one layer of the n-type work function metal will be used over the second fin 210 _(B) of the n-type FinFET.

As another example, the first fin 210 _(A) may be part of an n-type FinFET and the second fin 210 _(B) may be part of a p-type FinFET. In this example, the three work function layers over the first fin 210 _(A) may be, for example, two layers of n-type work function metals (such as TiAl or other n-type work function metals) and one layer of a p-type work function metal (such as TiN or other p-type work function metals), whereas the one layer of the p-type work function metal will be used over the second fin 210 _(B) of the p-type FinFET. Other materials, processes, and configurations may be utilized within the scope of the present disclosure.

The steps shown in FIGS. 1 through 20B are also reflected schematically in the process flow shown in FIG. 21.

FIG. 1 illustrates a perspective view of an initial structure. The initial structure includes a substrate 102 having semiconductor strips 106 extending therefrom. The respective step is illustrated as step 202 in the process flow shown in FIG. 21. The substrate 102 is formed of a semiconductor material having a first lattice constant. As will be explained in greater detail below, another semiconductor layer having a second lattice constant, different than the first lattice constant, will be formed over material of the substrate 102. In some embodiments, the substrate 102 comprises a crystalline silicon substrate (e.g., wafer), although other suitable elemental semiconductor, such as a suitable compound semiconductor (e.g., gallium arsenide, silicon carbide, indium arsenide, indium phosphide, or the like), or a suitable alloy semiconductor (e.g., silicon germanium carbide, gallium arsenic phosphide, or gallium indium phosphide), or the like, may also be used. Further, the substrate 102 may include an epitaxial layer (epi-layer), may be strained for performance enhancement, and/or may include a silicon-on-insulator (SOI) structure.

Furthermore, the substrate 102 may include other features. For example, the substrate may include various doped regions depending on design requirements (e.g., p-type substrate or n-type substrate). For example, the doped regions may be doped with p-type dopants, such as boron or BF₂, n-type dopants, such as phosphorus or arsenic, and/or combinations thereof. The doped regions may be configured for an n-type FinFET and/or a p-type FinFET.

The substrate 102 may be patterned using, for example, photolithography techniques. For example, a mask layer (not shown), such as a pad oxide layer and an overlying pad nitride layer, is formed over the substrate 102. The pad oxides layer may be a thin film comprising silicon oxide formed, for example, using a thermal oxidation process. The pad oxide layer may act as an adhesion layer between the substrate 102 and the overlying pad nitride layer and may act as an etch stop layer for etching the pad nitride layer. In an embodiment, the pad nitride layer is formed of silicon nitride, for example, using low-pressure chemical vapor deposition (LPCVD) or plasma enhanced chemical vapor deposition (PECVD).

The mask layer may be patterned using photolithography techniques. Generally, photolithography techniques utilize a photoresist material (not shown) that is deposited, irradiated (exposed), and developed to remove a portion of the photoresist material. The remaining photoresist material protects the underlying material, such as the mask layer in this example, from subsequent processing steps, such as etching. In this example, the photoresist material is patterned to define the pad oxide and pad nitride.

The patterned mask is subsequently used to pattern exposed portions of the substrate 102 to form trenches 104, thereby defining semiconductor strips 106 between adjacent trenches 104 as illustrated in FIG. 1. As will be discussed below, the trenches 104 will be subsequently filled with a dielectric material, forming isolation regions such as shallow trench isolation (STI) regions adjacent to the semiconductor strips 106. In some embodiments, the trenches 104 may be strips (viewed from in the top) parallel to each other, and closely spaced with respect to each other. In some embodiments, the trenches 104 may be continuous and surrounding the semiconductor strips 106.

Isolation regions, such as STI regions 108, may be formed to extend from a top surface of substrate 102 into substrate 102, wherein the top surface of substrate 102 is a major surface 102A of the substrate or wafer. The portions of substrate 102 between neighboring STI regions 108 are referred to as semiconductor strips 106. The top surfaces of semiconductor strips 106 and the top surfaces of STI regions 108 may be substantially level (within process variations) with each other in accordance with some exemplary embodiments.

STI regions 108 may include a liner oxide (not shown). The liner oxide may be formed of a thermal oxide formed through a thermal oxidation of a surface layer of substrate 102. The liner oxide may also be a deposited silicon oxide layer formed using, for example, Atomic Layer Deposition (ALD), High-Density Plasma Chemical Vapor Deposition (HDPCVD), or Chemical Vapor Deposition (CVD). STI regions 108 may also include a dielectric material over the liner oxide, wherein the dielectric material may be formed of Flowable Chemical Vapor Deposition (FCVD), spin-on, or the like.

In some embodiments, the STI regions 108 may be a silicon oxide layer formed using an HDPCVD process, using silane (SiH₄) and oxygen (O₂) as reacting precursors. In other embodiment, the STI regions 108 may be formed using a sub-atmospheric CVD (SACVD) process or high aspect-ratio process (HARP), wherein process gases may comprise tetraethylorthosilicate (TEOS) and ozone (O₃). In yet other embodiments, the STI regions 108 may be formed using a spin-on-dielectric (SOD) process, such as hydrogen silsesquioxane (HSQ) or methyl silsesquioxane (MSQ). Other processes and materials may be used. A planarization process, such as a chemical mechanical polish (CMP) process, may be performed to remove excess materials to form the STI regions 108 as illustrated in FIG. 1.

Referring to FIG. 2, STI regions 108 are recessed, so that top portions of semiconductor strips 106 protrude higher than the top surfaces of STI regions 108 to form protruding fins 210. The respective step is illustrated as step 204 in the process flow shown in FIG. 21. The etching may be performed using one or more etching processes. For example, a dry etching process using NF₃ and NH₃ as the etching gases may be used in embodiments in which the STI regions 108 are formed of silicon oxide. Argon may also be included. In accordance with alternative embodiments of the present disclosure, the recessing of STI regions 108 may be performed using a wet etch process, such as a diluted HF wet etch.

Referring to FIG. 3, dummy gate stack 310 is formed on the top surfaces and the sidewalls of protruding fins 210. The respective step is illustrated as step 206 in the process flow shown in FIG. 21. Dummy gate stack 310 may include dummy gate dielectric 312 and dummy gate electrode 314 over dummy gate dielectric 312. Dummy gate electrode 314 may be formed, for example, using polysilicon, but other materials may also be used. Dummy gate stack 310 may also include one or more hard masks, such as hard mask 316, over dummy gate electrode 314. Hard mask layer 316 may be formed of silicon nitride, silicon carbo-nitride, or the like. Dummy gate stack 310 may also have a lengthwise direction substantially perpendicular (e.g., within process variations) to the lengthwise or longitudinal direction of protruding fins 210.

Next, gate spacers 318 are formed on the sidewalls of dummy gate stack 310. In accordance with some embodiments of the present disclosure, gate spacers 318 are formed of a dielectric material such as silicon nitride, silicon oxy-carbo-nitride (SiOCN), silicon carbon-nitride (SiCN), or a metal oxide such as aluminum oxide. In accordance with some embodiments of the present disclosure, spacer layer is formed of SiOCN, and may have a single-layer structure. In accordance with alternative embodiments, spacer layer has a composite structure including a plurality of layers. For example, spacer layer may include a silicon oxide layer, and a silicon nitride layer over the silicon oxide layer.

The gate spacers 318 may be formed by anisotropically etching a blanket-deposited layer. In accordance with some embodiments of the present disclosure, a spacer layer (not shown) is formed using a conformal deposition method such as ALD, CVD, etc., so that the sidewall portions of spacer layer have an adequate thickness. The horizontal portions and vertical portions of spacer layer may have substantially the same thickness, for example, with the vertical thickness of the vertical portions and the horizontal thickness of the horizontal portions having a difference smaller than 20 percent of the horizontal thickness.

An anisotropic etching is performed to remove the horizontal portions of spacer layer. The remaining vertical portions of spacer layer form gate spacers 318 on the sidewalls of dummy gate stack 310. Though not shown, portions of the spacer layer may remain adjacent to the protruding fins 210.

As illustrated in FIG. 4, an etching step (referred to as source/drain recessing hereinafter) is then performed to etch portions of protruding fins 210 that are not covered by dummy gate stack 310 and dummy gate spacers 318 in accordance with some embodiments. The respective step is illustrated as step 208 in the process flow shown in FIG. 21. The recessing may be anisotropic, and hence the portions of fins 210 directly underlying dummy gate stack 310 and dummy gate spacers 318 are protected and are not etched. The top surfaces of the recessed semiconductor strips 106 may be lower than the top surfaces of STI regions 108 in accordance with some embodiments. Recesses 410 are accordingly formed between STI regions 108. Recesses 410 are located on opposite sides of dummy gate stack 310.

Next, as illustrated in FIG. 5, source/drain regions 510 are formed. The source/drain regions may be formed using an epitaxial process to selectively grow a semiconductor material in recesses 410 (see FIG. 4). The respective step is illustrated as step 210 in the process flow shown in FIG. 21. In accordance with some exemplary embodiments, source/drain regions 510 include silicon germanium or silicon. Depending on whether the resulting FinFET is a p-type FinFET or an n-type FinFET, the epitaxy regions may be in situ doped with a p-type or an n-type impurity. For example, when the resulting FinFET is a p-type FinFET, silicon germanium boron (SiGeB) may be grown. Conversely, when the resulting FinFET is an n-type FinFET, silicon phosphorous (SiP) or silicon carbon phosphorous (SiCP) may be grown. In accordance with alternative embodiments of the present disclosure, epitaxy regions comprise III-V compound semiconductors such as GaAs, InP, GaN, InGaAs, InAlAs, GaSb, AlSb, AlAs, AlP, GaP, combinations thereof, or multi-layers thereof. After recesses 410 are filled with epitaxy regions, the further epitaxial growth of epitaxy regions causes epitaxy regions to expand horizontally, and facets may be formed.

After the epitaxy step, epitaxy regions may be further implanted with a p-type or an n-type impurity to form source/drain regions 510. In accordance with alternative embodiments of the present disclosure, the epitaxy regions are in-situ doped with the p-type or n-type impurity during the epitaxy process, and the implantation step is skipped. Epitaxy regions include lower portions that are formed in STI regions 108, and upper portions that are formed over the top surfaces of STI regions 108. Lower portions, whose sidewalls are shaped by the shapes of recesses 410 (FIG. 4), may have (substantially) straight edges, which may also be substantial vertical edges that are substantially perpendicular to the major surfaces of substrate 102.

FIG. 6 illustrates a perspective view of the structure after silicide regions 608 and an Inter-Layer Dielectric (ILD) 610 are formed. The respective step is illustrated as step 212 in the process flow shown in FIG. 21. Source/drain silicide regions 608 are formed on the surfaces of source/drain regions 510. The formation process includes depositing a metal layer on the source/drain regions 510, and performing an anneal to react the metal layer with the exposed surface portions of epitaxy regions, so that silicide regions 608 are formed.

The ILD 610 may comprise a single layer or multiple layers. For example, in some embodiments an ILD liner (not shown) is deposited, and an ILD filler material is deposited over the ILD liner. In some embodiments, the ILD liner comprises SiO₂, SiCN, SiON, Si₃N₄, and SiN_(x)H_(y), but other suitable dielectric materials may be used. The ILD liner may further comprise a plurality of layers that comprise combinations of the above mentioned materials. The ILD liner may be deposited through one or more processes such as PVD, CVD, or ALD, although any acceptable process may be utilized. Other materials and/or processes may be used.

In some embodiments, the ILD filler material comprises SiO₂, SiCN, SiOC, SiON, Si₃N₄, and SiN_(x)H_(y), but other suitable dielectric film may be used. The isolation dielectric may be cured or treated after deposition. For example, the curing may involve irradiation with ultra-violet radiation, and the treatment may involve annealing in N₂, O₂, or H₂O ambient at temperatures ranging above 200° C. After the curing or treatment, the isolation dielectric may have a relative permittivity of less than 6, such as less than 5, and such as less than 4. For example, the isolation dielectric may be SiO₂ formed by CVD, PECVD or ALD deposition process, FCVD, or a spin-on-glass process. A planarization process, such as a CMP process, may be performed to remove excess materials and to expose dummy gate stack 310.

As illustrated in FIG. 7, portions of the ILD 610 are removed to form source/drain contacts 710. The respective step is illustrated as step 214 in the process flow shown in FIG. 21. The ILD 610 may be patterned to form openings to expose the source/drain regions 510/silicide regions 608 using photolithography processes in combination with one or more etching processes. In embodiments in which the ILD 610 is formed of silicon oxide, the etch process may be, for example, a dry etch, a chemical etch, or a wet cleaning process. For example, the chemical etch may employ fluorine-containing chemical such as dilute hydrofluoric (dHF) acid. Other materials and/or processes may be used.

Thereafter, the openings may be filled with one or more conductive layers to form the source/drain contacts 710. The source/drain contacts 710 may comprise a single layer or a multi-layer structure. For example, in some embodiments the source/drain contacts 710 comprise a liner, such as a diffusion barrier layer, an adhesion layer, or the like, and a contact filler formed over the contact liner in the openings. The contact liner may include Ti, TiN, Ta, TaN, or the like formed by ALD, CVD, or the like. The contact filler may be formed by depositing a conductive material, such as one or more layers of Ni, Ta, TaN, W, Co, Ti, TiN, Al, Cu, Au, alloys thereof, combinations thereof, or the like, but other suitable metal may be used. A planarization process, such as a CMP, may be performed to remove excess material from a surface of the ILD 610, thereby forming the contacts as illustrated in FIG. 7.

The above process generally describes a FinFET structure and a method of forming for illustration purposes. Other structures and processes may be used. For example, multiple epitaxial regions and different fin/epitaxial shapes may be used. Additionally, while the structure and the figures described above illustrate a single fin for each of the source/drain regions, multiple fins may share a common source/drain region, in which the epitaxial regions are separated or grown together. The epitaxial regions grown together may have faceted upper surfaces or relatively flat upper surfaces, and may include voids between the epitaxial regions and the ILD. As another example, different or additional spacer structures, masks, liners, and the like may be used.

As will be described in greater detail below with reference to FIGS. 8A-20B, the dummy gate stack 310 will be replaced with a metal gate structure, whereas the “A” labeled figures are plan views of the area around the dummy gate stack 310 as illustrated in FIG. 7, and the “B” labeled figures are taken along the B-B′ cross section illustrated in FIG. 7. Moreover, one or more work function layers will be formed over each of the fins 210, such that the work function layers are adjusted for the particular desired electrical characteristics of each transistor. For example, in some situations in a PMOS transistor and an NMOS transistor may have a shared gate, such as for an inverter, but the work function layers of the NMOS transistor may be tuned independently of the PMOS transistor to increase performance of each transistor. As such, the following discussion describes a device and a method of manufacturing a device in which two transistors share a common gate, but have different work function layers.

Referring first to FIGS. 8A and 8B, there is shown for reference the plan view and cross-sectional view, respectively, of the structure illustrated in FIG. 7 for reference prior to proceeding further with processing.

Thereafter, as illustrated in FIGS. 9A and 9B, the dummy gate stack 310 (see FIGS. 8A and 8B), including hard mask layer 316, dummy gate electrode 314, and dummy gate dielectric 312, are removed, thereby forming a recess 910. The respective step is illustrated as step 216 in the process flow shown in FIG. 21. The removal process may comprise one or more etch processes. For example in embodiments in which the ILD 610 comprises silicon oxide, the hard mask 316 comprises silicon nitride, the dummy gate electrode 314 comprises polysilicon, and the dummy gate dielectric 312 comprises silicon oxide, the removal process may comprise selectively etching using either dry or wet etching. In this example, the hard mask layer 316 may be removed by using a dry etch with a process gas including CF₄, CHF₃, CH₂F₂, CH₃F, NF₃, SF₆, or combinations thereof, and the dummy gate electrode 314 may be removed using a dry etch with a process gas including CF₄, CHF₃, NF₃, SF₆, Br₂, HBr, Cl₂, or combinations thereof. Diluting gases such as N₂, O₂, or Ar may optionally be used. In the case wet etching is used to remove the dummy gate electrode 314, the chemicals may include NH₄OH:H₂O₂:H₂O (APM), NH₂OH, KOH, HNO₃:NH₄F:H₂O, and/or the like. The dummy gate dielectric 312 may be removed using a wet etch process, such as a diluted HF acid. Other processes and materials may be used. In some embodiments, the recess 910 may have a width W1 of about 10 nm to about 300 nm, and a length L1 of about 100 nm to about 2000 nm.

Next, referring to FIGS. 10A and 10B, one or more gate dielectric layers 1010 is formed over a channel region of the fins 210 in accordance with some embodiments. The respective step is illustrated as step 218 in the process flow shown in FIG. 21. In an embodiment, the gate dielectric layer 1010 includes one or more high-k dielectric layers (e.g., having a dielectric constant greater than 3.9) and may be formed as a conformal layer extending along the sidewalls of protruding fins 210 and the top surface and the sidewalls of gate spacers 318 and the ILD 610. (The gate dielectric layers 1010 are not illustrated over the gate spacers 318 and the ILD 610 in the plan view of the “A” figures for ease of illustration.) For example, the one or more gate dielectric layers may include one or more layers of a metal oxide or a silicate of Hf, Al, Zr, combinations thereof, and multi-layers thereof. Other suitable materials include La, Mg, Ba, Ti, Pb, Zr, in the form of metal oxides, metal alloyed oxides, and combinations thereof. Exemplary materials include MgO_(x), BaTi_(x)O_(y), BaSr_(x)Ti_(y)O_(z), PbTi_(x)O_(y), PbZr_(x)TiO_(z), SiCN, SiON, Si₃N₄, Al₂O₃, La₂O₃, Ta₂O₃, Y₂O₃, HfO₂, ZrO₂, HfSiON, YGe_(x)O_(y), YSi_(x)O_(y) and LaAlO₃, and the like. The formation methods of gate dielectric layer 1010 include molecular-beam deposition (MBD), ALD, PVD, and the like. In an embodiment, the gate dielectric layer 1010 may have a thickness of about 10 Å to about 25 Å.

In some embodiments, an interfacial layer (not shown) may be formed over the channel region of the fins 210 prior to forming the gate dielectric layer 1010, and the gate dielectric layer 1010 is formed over the interfacial layer. The interfacial layer helps buffer the subsequently formed high-k dielectric layer from the underlying semiconductor material. In some embodiments, the interfacial layer is a chemical silicon oxide, which may be formed of chemical reactions. For example, a chemical oxide may be formed using deionized water+ozone (DIO₃), NH₄OH+H₂O₂+H₂O (APM), or other methods. Other embodiments may utilize a different material or processes (e.g., a thermal oxidation or a deposition process) for the interfacial layer. In an embodiment, the interfacial layer may have a thickness of about 3 Å to about 7 Å. The interfacial layer and/or the gate dielectric layers 1010 may extend only over the fin 210 (e.g., not over the STI regions 108, the gate spacers 318, or the ILD 610), depending on the material and the processes used to form those layers.

Thereafter, as illustrated in FIGS. 11A and 11B, a first work function (WF) layer 1110 is formed over the fins 210. The respective step is illustrated as step 218 in the process flow shown in FIG. 21. As will be described in greater detail below, a work function structure comprising one or more metal layers will be formed over the fins 210, wherein the work function metal will be patterned for each particular transistor. The work function of the gate electrode may be adjusted to the band-edge of silicon or other underlying semiconductor material. For an NMOS device, the work function may be adjusted to close to the conduction band of silicon, and for a PMOS device, the work function may be adjusted to close to the valence band of silicon, to increase the performance of the transistors.

In an embodiment, the first work function layer 1110 is formed through deposition, such as a conformal deposition method such as ALD or CVD, so that the horizontal thickness T₁ of the horizontal portions and vertical thickness T₂ of vertical portions have thicknesses substantially equal to each other. For example, horizontal thickness T₁ and vertical thickness T₂ may have a difference smaller than about 20 percent or 10 percent of thickness T₁. The thickness T₁ may be in the range between about 5 Å and about 30 Å.

FIGS. 12A-12B illustrate formation of a first mask 1220 to subsequently pattern the first WF layer 1110 in accordance with some embodiments. The respective step is illustrated as step 220 in the process flow shown in FIG. 21. The first mask 1220 may comprise one or more layers of a masking material. For example, FIGS. 12A and 12B illustrate a first sacrificial layer 1222 formed over the first WF layer 1110. The first sacrificial layer 1222 may be formed of a bottom antireflective coating (BARC). Generally, during photolithography patterning, light may be reflected off the surface of the underlying material and back into the photoresist material during the exposure process, wherein the reflected light may alter the intended pattern of the photoresist. A BARC layer formed of a material having the appropriate refractive index n to limit or prevent reflection of the exposing light back into the photoresist material. In some embodiments, the first sacrificial layer 1222 may be formed of, for example, a dielectric, an organic material, or the like, and may be formed by, for example, spin coating, PECVD, CVD, or the like. In some embodiments, the first sacrificial layer 1222 may be a resist underlayer film as described in U.S. Pat. No. 8,481,247, which is incorporated herein by reference in its entirety. Additionally, the first mask 1220 may comprise one or more additional masking layers, such as the first patterned mask 1224. In some embodiments, the first patterned mask 1224 may be a photoresist exposed and developed to form the pattern as illustrated in FIGS. 12A and 12B. Additional masks, such as a silicon oxide, silicon nitride, combinations thereof, or the like may be used in addition to, or instead of, the photoresist mask to provide additional protections during etching.

As illustrated in FIGS. 12A and 12B, a first edge 1224 ₁ of the first patterned mask 1224 is shifted from a center line C between the adjacent fins, indicated in the figures as a first fin 210 _(A) and a second fin 210 _(B), toward the first fin 210 _(A) by a distance D₂. As discussed in greater detail below with reference to FIGS. 16A and 16B, shifting the first edge 1224 ₁ of the first patterned mask 1224 toward the first fin 210 _(A) allows subsequent masks to provide better coverage and provide more uniform patterning of subsequent WF layers.

In some embodiments, a distance D₁ between the first fin 210 _(A) and the second fin 210 _(B) is about 30 nm to about 100 nm, and a shift distance D₂ is between about 6 nm and about 40 nm. In some embodiments, the shift distance is about 20% to about 40% of the distance D₁ between the first fin 210 _(A) and the second fin 210 _(B).

Next, as shown in FIGS. 13A and 13B, the first patterned mask 1224 is used as an etching mask to pattern the first sacrificial layer 1222 and the first work function layer 1110. The respective step is illustrated as step 220 in the process flow shown in FIG. 21. In embodiments in which the first sacrificial layer 1222 is formed of bottom antireflective coating, the first sacrificial layer 1222 may be etched using a dry etch process, or other suitable etching processes, may be used. In the case dry etching is used, the process gas may include N₂, O₂, CH₄, CF₄, CHF₃, NF₃, SF₆, Br₂, HBr, Cl₂, or combinations thereof. Diluting gases such as N₂, O₂, or Ar may optionally be used. In some embodiments, the sacrificial layer 1222 may be patterned as the resist underlayer film described in U.S. Pat. No. 8,481,247, which is incorporated herein by reference in its entirety. Thereafter, a wet etch process, or other suitable etching processes, may be used to pattern the underlying first work function layer 1110. For example, in embodiments in which the first work function layer 1110 is formed of TiN, a wet etching process using NH₄OH+H₂O₂+H₂O (APM), and/or the like, may be used. Other processes and materials may be used.

FIGS. 14A and 14B illustrate removal of the first patterned mask 1224 and the first sacrificial layer 1222. The respective step is illustrated as step 220 in the process flow shown in FIG. 21. In an embodiment in which the first patterned mask 1224 is formed of a patterned photoresist, the first patterned mask 1224 may be removed using an ashing process in an ambient of N₂, H₂, O₂ and a temperature of about 150° C. to about 350° C. In an embodiment in which the first sacrificial layer 1222 is formed of bottom antireflective coating, the first sacrificial layer 1222 may be removed using, for example, an ashing process in an ambient of N₂, H₂, O₂ and a temperature of about 150° C. to about 350° C. In some embodiments, an edge of the first work function layer 1010 extends a distance D₃ from the first fin 210 _(A) as illustrated in FIG. 14B of about 10 nm to about 40 nm.

Thereafter, as illustrated in FIGS. 15A and 15B, a second WF layer 1510 is formed over the first WF layer 1110 in the area of the first fin 210 _(A) and over the second fin 210 _(B). The respective step is illustrated as step 222 in the process flow shown in FIG. 21. In an embodiment, the second WF layer 1510 is formed through deposition, such as a conformal deposition method such as ALD or CVD, so that the horizontal thickness T₃ of the horizontal portions and vertical thickness T₄ of vertical portions of second work function layer 1510 have thicknesses substantially equal to each other. For example, horizontal thickness T₃ and vertical thickness T₄ may have a difference smaller than about 20 percent or 10 percent of thickness T₃. The thickness T₃ may be in the range between about 5 Å and about 50 Å.

FIGS. 16A-16B illustrate formation of a second mask 1620 to subsequently pattern the second WF layer 1510 in accordance with some embodiments. The respective step is illustrated as step 224 in the process flow shown in FIG. 21. The second mask 1620 may comprise one or more layers of a masking material. For example, FIGS. 16A and 16B illustrate a second sacrificial layer 1622 formed over the second WF layer 1510. The second sacrificial layer 1622 may be formed of a BARC, which may be formed of similar materials and by similar processes as discussed above with reference to the first sacrificial layer 1222. Additionally, the second mask layer 1620 may comprise one or more additional masking layers, such as the second patterned mask 1624. In some embodiments, the second patterned mask 1624 may be a photoresist exposed and developed to form the pattern as illustrated in FIGS. 16A and 16B. Additional masks, such as a silicon oxide, silicon nitride, combinations thereof, or the like may be used in addition to, or instead of, the photoresist mask to provide additional protections during etching.

As illustrated in FIGS. 16A and 16B, the second patterned mask 1624 is shifted from a center line C between the first fin 210 _(A) and the second fin 210 _(B) toward the second fin 210 _(B). In some embodiments, the dimensions of the opening in the ILD 610 after forming various layers (e.g., the first WF layer 1110 and the second WF layer 1510) may hinder or prevent the subsequent mask from sufficiently covering and protecting the underlying layers during a subsequent etch process. As a result, voids may form in, for example, the second sacrificial layer 1622, and during an etch process to pattern the second WF layer 1510 the voids in the second sacrificial layer 1622 mask layer may allow etchants to undesirably remove portions of the second WF layer 1510 over the first fin 210 _(A). For illustrative purposes, a void is illustrated in FIG. 16B by the dotted region indicated by reference numeral 1650. As illustrated, by shifting the edge 1224 ₁ of the first patterned mask 1224 toward the first fin 210A and shifting an edge 1624 ₁ of the second patterned mask 1624 toward the second patterned mask 210B, sufficient amounts of the second sacrificial layer 1622 remains to prevent etching into the void 1650 and into the work function layers.

In some embodiments, a shift distance D₄ from the center line C toward the second fin 210 _(E) is between about 6 nm and about 40 nm. In some embodiments, the shift distance D₄ is about 20% to about 40% of the distance D₁ between the first fin 210 _(A) and the second fin 210 _(B). In some embodiments, an edge of the second work function layer 1510 extends a distance D₅ from the first fin 210 _(A) as illustrated in FIG. 17B of about 20 nm to about 90 nm.

Next, as shown in FIGS. 17A and 17B, the second patterned mask 1624 is used as an etching mask to pattern the second sacrificial layer 1622 and the second WF layer 1510. The respective step is illustrated as step 224 in the process flow shown in FIG. 21. In embodiments in which the second sacrificial layer 1622 is formed of bottom antireflective coating, the second sacrificial layer 1622 may be etched using a dry etch process, or other suitable etching processes, may be used. In the case dry etching is used, the process gas may include N₂, O₂, CH₄, CF₄, CHF₃, NF₃, SF₆, Br₂, HBr, Cl₂ or combinations thereof. Diluting gases such as N₂, O₂, or Ar may optionally be used. In some embodiments, the sacrificial layer 1222 may be patterned as the resist underlayer film described in U.S. Pat. No. 8,481,247, which is incorporated herein by reference in its entirety. Thereafter, a wet etch process, or other suitable etching processes, may be used to pattern the underlying second work function layer 1510. For example, in embodiments in which the second work function layer 1510 is formed of TiN, a wet etching process using NH₄OH+H₂O₂+H₂O (APM), and/or the like, may be used. Other processes and materials may be used.

FIGS. 18A and 18B illustrate removal of the second patterned mask 1624 and the second sacrificial layer 1622. The respective step is illustrated as step 224 in the process flow shown in FIG. 21. In an embodiment in which the second patterned mask 1624 is formed of a patterned photoresist, the second patterned mask 1624 may be removed using an ashing process in an ambient of N₂, H₂, or O₂ and a temperature of about 150° C. to about 300° C. In an embodiment in which the second sacrificial layer 1622 is formed of bottom antireflective coating, the second sacrificial layer 1622 may be removed using, for example, an ashing process in an ambient of N₂, H₂, or O₂, and a temperature of about 150° C. to about 350° C.

Thereafter, as illustrated in FIGS. 19A and 19B, a third work function layer 1910 is formed over the second work function layer 1510 in the area of the first fin 210 _(A) and over the second fin 210 _(B). The respective step is illustrated as step 226 in the process flow shown in FIG. 21. In an embodiment, the third work function layer 1910 is formed through deposition, such as a conformal deposition method such as ALD or CVD, so that the horizontal thickness T₅ of the horizontal portions and vertical thickness T₆ of vertical portions of third work function layer 1910 have thicknesses substantially equal to each other. For example, horizontal thickness T₅ and vertical thickness T₆ may have a difference smaller than about 20 percent or 10 percent of thickness T₅. The thickness T₅ may be in the range between about 5 Å and about 50 Å.

FIGS. 20A and 20B illustrate filling the remaining opening with a gate electrode 2020 in accordance with an embodiment. The respective step is illustrated as step 228 in the process flow shown in FIG. 21. The gate electrode 2020 may be a metal selected from a group of W, Cu, Ti, Ag, Al, TiAl, TiAlN, TaC, TaCN, TaSiN, Mn, Co, Pd, Ni, Re, Ir, Ru, Pt, and Zr. In some embodiments, the gate electrode 2020 comprises a metal selected from a group of TiN, WN, TaN, and Ru. Metal alloys such as Ti—Al, Ru—Ta, Ru—Zr, Pt—Ti, Co—Ni and Ni—Ta may be used and/or metal nitrides such as WN_(x), TiN_(x), MoN_(x), TaN_(x), and TaSi_(x)N_(y) may be used. In some embodiments, the gate electrode 2020 has a thickness in the range of about 5 nm to about 100 nm. The gate electrode 2020 may be formed using a suitable process such as ALD, CVD, PVD, plating, or combinations thereof. A planarization process, such as a CMP, may be performed to remove excess materials of the gate dielectric 1010, the first work function layer 1110, the second work function layer 1510, the third work function layer 1910, and the gate electrode 2020 from the upper surface of the ILD 610.

Other processes may be performed. For example, additional dielectric layers may be formed and metallization layers may be formed to interconnect the various transistors and/or other devices to form circuits, external connectors may be formed, a singulation process may be performed, and/or the like.

The materials and processes describe an example in which the fin 210 _(A) is a PMOS transistor having three work function layers and fin 210 _(B) is a NMOS transistor having one work function layer. For example, fin 210 _(A) may be a PMOS transistor having three work function layers, wherein the first work function layer is TiN or other p-type metal, the second work function layer is TiN or other p-type metal, and the third work function layer is TiAl or other n-type metal. In this example, the fin 210 _(B) may be a NMOS having a single work function layer of TiAl or other n-type metal.

As another example in which the fin 210 _(A) is an NMOS transistor having three work function layers and fin 210 _(B) is a PMOS transistor having one work function layer. Other materials and configuration may be used. For example, fin 210 _(A) may be an NMOS having three work function layers, wherein the first work function layer is TiAl or other n-type metal, the second work function layer is TiAl or other n-type metal, and the third work function layer is TiN or other p-type metal. In this example, the fin 210 _(B) may be a PMOS having a single work function layer of TiN or other P-type metal.

In accordance with an embodiment, a method is provided. The method includes forming a first dielectric layer over a first fin and a second fin; forming a recess in the first dielectric layer, the first fin and the second fin protruding above a bottom of the recess; forming a first work function layer over the first fin and the second fin; forming a first patterned mask over the first work function layer, the first patterned mask terminating closer to the first fin than the second fin such that the first work function layer over the second fin is exposed; removing the first work function layer from over the second fin and an area between the first fin and the second fin, the first work function layer terminating at a position closer to the first fin than the second fin; and removing the first patterned mask. A second work function layer is formed over the first work function layer and the second fin, a second patterned mask is formed over the second work function layer, the second patterned mask terminating closer to the second fin than the first fin such that the second work function layer over the second fin is exposed, the second work function layer is removed from over the second fin and an area between the first fin and the second fin, the second work function layer terminating at a position closer to the second fin than the first fin, and the second patterned mask is removed. The method further includes forming a third work function layer over the second work function layer and the second fin; and forming a metal layer over the third work function layer.

In accordance with an embodiment, a method is provided. The method includes forming a first work function layer over a first fin, the first work function layer terminating closer to the first fin than a second fin; forming a second work function layer over the first work function layer, the second work function layer terminating closer to the second fin than the first fin; forming a third work function layer over the second work function layer, the third work function layer extending over the second fin; and forming a metal layer over the third work function layer.

In accordance with an embodiment, a device is provided. The device includes a first fin; a second fin; a first work function metal layer extending over the first fin, the first work function metal layer terminating at a first location closer to the first fin than the second fin, the first location being between the first fin and the second fin; a second work function metal layer extending over the first work function metal layer, the second work function metal layer terminating at a second location closer to the second fin than the first fin, the second location being between the first fin and the second fin; and a gate electrode over the first fin and the second fin.

The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure. 

What is claimed is:
 1. A semiconductor device comprising: a first fin; a second fin, wherein a region between the first fin and the second fin is free of another fin, wherein the region extends from the first fin to the second fin; a first work function metal layer extending over the first fin, the first work function metal layer terminating at a first location closer to the first fin than the second fin, the first location being between the first fin and the second fin; a second work function metal layer extending over the first work function metal layer, the second work function metal layer terminating at a second location closer to the second fin than the first fin, the second location being between the first fin and the second fin; and a gate electrode over the first fin and the second fin.
 2. The semiconductor device of claim 1 further comprising a third work function metal layer over the first fin and the second fin, the gate electrode being over the third work function metal layer.
 3. The semiconductor device of claim 1, wherein the first work function metal layer terminates 20% to 40% of a distance between the first fin and the second fin from a mid-point between the first fin and the second fin toward the first fin.
 4. The semiconductor device of claim 3, wherein the second work function metal layer terminates 20% to 40% of the distance between the first fin and the second fin from the mid-point between the first fin and the second fin toward the second fin.
 5. The semiconductor device of claim 1, wherein the first work function metal layer terminates a distance of 10 nm to 40 nm from a sidewall of the first fin.
 6. The semiconductor device of claim 1 further comprising an interlayer dielectric over the first fin and the second fin, wherein the first work function metal layer extends to an upper surface of the interlayer dielectric.
 7. The semiconductor device of claim 6 further comprising gate spacers, the gate spacers separating the interlayer dielectric from the first work function metal layer.
 8. A semiconductor device comprising: a first dielectric layer over a first fin, a second fin, and an isolation region on opposing sidewalls of the first fin and the second fin; and a gate structure extending through the first dielectric layer to the first fin and the second fin, wherein the gate structure comprises: a gate dielectric layer over the first fin and the second fin; a first work function layer over the first fin, the first work function layer terminating at a first position closer to the first fin than the second fin; a second work function layer over the first fin and the first work function layer, the second work function layer terminating at a second position closer to the second fin than the first fin; a third work function layer over the first fin, the first work function layer, and the second fin; and a conductive fill over the first fin, the second fin, and the third work function layer.
 9. The semiconductor device of claim 8, wherein the first work function layer extends to an upper surface of the first dielectric layer.
 10. The semiconductor device of claim 8, wherein the gate dielectric layer separates the first work function layer from the first dielectric layer.
 11. The semiconductor device of claim 8, wherein the gate dielectric layer separates the first work function layer from the isolation region.
 12. The semiconductor device of claim 8 further comprising a spacer interposed between the first dielectric layer and the gate structure.
 13. The semiconductor device of claim 12, wherein the spacer completely surrounds the gate structure in a plan view.
 14. The semiconductor device of claim 8, wherein a distance from the first fin to the first position is in a range from 10 nm to 40 nm.
 15. The semiconductor device of claim 14, wherein a distance from the first fin to the second position is in a range from 20 nm to 90 nm.
 16. The semiconductor device of claim 8, wherein a distance from the first fin to the first position is 10% to 30% of a distance between the first fin and a mid-point between the first fin and the second fin.
 17. A semiconductor device comprising: a first fin; a second fin; isolation regions extending around the first fin and the second fin; an interlayer dielectric over the first fin, the second fin, and the isolation regions; a gate spacer extending through the interlayer dielectric; and a gate structure extending through the interlayer dielectric, the gate structure having a first end and a second end, the gate structure comprising: a gate dielectric layer extending through the interlayer dielectric, wherein the gate spacer is interposed between the gate dielectric layer and the interlayer dielectric at the first end and the second end; a first conductive layer over the gate dielectric layer, wherein the gate spacer is interposed between the first conductive layer and the interlayer dielectric at the first end, wherein a distance from the first fin to an end of the first conductive layer is less than a distance from the second fin to the end of the first conductive layer; a second conductive layer over the gate dielectric layer, wherein the gate spacer is interposed between the second conductive layer and the interlayer dielectric at the first end, wherein a distance from the first fin to an end of the second conductive layer is greater than a distance from the second fin to the end of the second conductive layer; and a third conductive layer over the second conductive layer, wherein an upper surface of the third conductive layer is level with an upper surface of the interlayer dielectric.
 18. The semiconductor device of claim 17 further comprising a fourth conductive layer interposed between the third conductive layer and the second conductive layer, wherein the fourth conductive layer directly contacts the gate dielectric layer.
 19. The semiconductor device of claim 17, wherein a distance from a mid-point between the first fin and the second fin to the second conductive layer is 20% to 40% of a distance between to the first fin and the second fin.
 20. The semiconductor device of claim 17, wherein an upper surface of the first conductive layer and an upper surface of the second conductive layer are level with the upper surface of the third conductive layer. 